Accounts, and so licences/keys, are tied to the email address that they were purchased/registered with.
Presumably you were sent a key that you then registered in CCleaner to activate it as Pro.
So that key must have been sent to a valid email address that you had access to at that time.
That is the email address that you need to use when accessing or talking about your account.
If you have changed your email since you purchased/registered (perhaps losing access to the old email) then you need to let Support know that, giving both old and new emails.
They need that old one to find the account.
As presumably you can still see your key in CCleaner itself then is there a particular problem that we may be able to help with here?
(Or is this a case of wanting to cancel the auto-renewal?)